New stable isomorphous Ag34 and Ag33Au nanoclusters with an open shell electronic structure

Author:

Xi Xiao-Juan1234,Yang Jin-Sen1234,Wang Jia-Yin1234,Dong Xi-Yan12345,Zang Shuang-Quan1234ORCID

Affiliation:

1. College of Chemistry and Molecular Engineering

2. Zhengzhou University

3. Zhengzhou 450001

4. China

5. College of Chemistry and Chemical Engineering

Abstract

A novel stable 3-electron nanocluster Ag34 was assembled for the first time by the oxidation of a thiol, the central Ag atom of which was replaced with a Au atom, forming another alloyed nanocluster Ag33Au, causing a change in the optical absorbance and electrochemical energy gap.

Funder

National Natural Science Foundation of China

Zhengzhou University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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