Photoabsorbance of supported metal clusters: ab initio density matrix and model studies of large Ag clusters on Si surfaces

Author:

Vazhappilly Tijo1,Kilin Dmitri S.2ORCID,Micha David A.3ORCID

Affiliation:

1. Theoretical Chemistry Section, Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400 085, India

2. Department of Chemistry and Biochemistry, North Dakota State University, Fargo, ND 58102, USA

3. Departments of Chemistry and of Physics, Quantum Theory Project, University of Florida, Gainesville, Florida 32611, USA

Abstract

Silver metal clusters supported by a silicon solid surface show molecular electronic structure requiring ab initio treatments, and they also can display collective electronic phenomena similar to plasmons in metal solids.

Funder

National Science Foundation

University of Florida

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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