Multifaceted behavior of a doubly reduced arylborane in B–H-bond activation and hydroboration catalysis-Reference-Cited by-同舟云学术

Multifaceted behavior of a doubly reduced arylborane in B–H-bond activation and hydroboration catalysis

Published:2023 Issue:4 Volume:14 Page:849-860
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Prey Sven E.¹,Herok Christoph²^ORCID,Fantuzzi Felipe²³^ORCID,Bolte Michael¹^ORCID,Lerner Hans-Wolfram¹^ORCID,Engels Bernd²^ORCID,Wagner Matthias¹^ORCID

Affiliation:

1. Institut für Anorganische und Analytische Chemie, Goethe-Universität Frankfurt, Frankfurt am Main D-60438, Germany

2. Institut für Physikalische und Theoretische Chemie, Julius-Maximilians-Universität Würzburg, Würzburg D-97074, Germany

3. School of Chemistry and Forensic Science, University of Kent, Canterbury CT2 7NH, UK

Abstract

Alkali-metal salts of a 9,10-diboraanthracene dianion catalyze the hydroboration of CC-, CN-, and CO-containing compounds with pinacolborane. The actual reaction mechanism is highly substrate-dependent.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D2SC05518J

Reference60 articles.

1. G.Erker and D. W.Stephan , Frustrated Lewis Pairs I & II , Springer , Heidelberg , 2013

2. New Directions for Frustrated Lewis Pair Chemistry

3. Threat to the Throne: Can Two Cooperating Boron Atoms Rival Transition Metals in Chemical Bond Activation and Catalysis?

4. Small molecule activation by boron-containing heterocycles

5. 1,3,2,5-Diazadiborinine featuring nucleophilic and electrophilic boron centres

Cited by 9 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Unique Double and Triple Decker Arrangements of Rare‐Earth 9,10‐Diborataanthracene Complexes Featuring Single‐Molecule Magnet Characteristics;Angewandte Chemie International Edition;2024-03-22

2. Unique Double and Triple Decker Arrangements of Rare‐Earth 9,10‐Diborataanthracene Complexes Featuring Single‐Molecule Magnet Characteristics;Angewandte Chemie;2024-03-22

3. Aromaticity transfer in an annulated 1,4,2-diazaborole: facile access to C_s symmetric 1,4,2,5-diazadiborinines;Chemical Communications;2024

4. Juggling Optoelectronics and Catalysis: The Dual Talents of Bench Stable 1,4‐Azaborinines;Chemistry – A European Journal;2023-12-22

5. Hydroboration Reduction of CO₂ Catalyzed by a Doubly Reduced Arylborane: DFT Insight into Double Active-Site and CO₂ Self-Promoting Single Active-Site Mechanisms and Counterion Effects;ACS Catalysis;2023-12-19