Affiliation:
1. School of Chemical & Physical Sciences Keele University Newcastle-under-Lyme, Staffs ST5 5BG U.K.
Abstract
AbstractBoron‐ and nitrogen‐doped polycyclic aromatic hydrocarbons (B‐PAHs) have established a strong foothold in the realm of organic electronics. However, their catalytic potential remains largely untapped. In this study, we synthesise and characterise two bench stable B,N‐doped PAH derivatives based on a 1,4‐azaborinine motif. Most importantly, the anthracene derived structure is an efficient catalyst in the reduction of various carbonyls and imines. These results underscore the potential of B,N‐PAHs in catalytic transformations, setting the stage for deeper exploration in this chemical space.
Funder
Engineering and Physical Sciences Research Council
European Regional Development Fund
Subject
General Chemistry,Catalysis,Organic Chemistry