Juggling Optoelectronics and Catalysis: The Dual Talents of Bench Stable 1,4‐Azaborinines

Author:

van Beek Chloe M.1,Swarbrook Amelia M.1,Creissen Charles E.1,Hawes Chris S.1,Gazis Theodore A.1,Matthews Peter D.1ORCID

Affiliation:

1. School of Chemical & Physical Sciences Keele University Newcastle-under-Lyme, Staffs ST5 5BG U.K.

Abstract

AbstractBoron‐ and nitrogen‐doped polycyclic aromatic hydrocarbons (B‐PAHs) have established a strong foothold in the realm of organic electronics. However, their catalytic potential remains largely untapped. In this study, we synthesise and characterise two bench stable B,N‐doped PAH derivatives based on a 1,4‐azaborinine motif. Most importantly, the anthracene derived structure is an efficient catalyst in the reduction of various carbonyls and imines. These results underscore the potential of B,N‐PAHs in catalytic transformations, setting the stage for deeper exploration in this chemical space.

Funder

Engineering and Physical Sciences Research Council

European Regional Development Fund

Publisher

Wiley

Subject

General Chemistry,Catalysis,Organic Chemistry

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