Thermolysis of 1,3-dioxin-4-ones: fast generation of kinetic data using in-line analysis under flow-Reference-Cited by-同舟云学术

Thermolysis of 1,3-dioxin-4-ones: fast generation of kinetic data using in-line analysis under flow

Published:2016 Issue:1 Volume:1 Page:82-89
ISSN:2058-9883
Container-title:Reaction Chemistry & Engineering
language:en
Short-container-title:React. Chem. Eng.

Author:

Durand Thomas¹²³⁴,Henry Cyril¹²³⁴,Bolien David¹²³⁴,Harrowven David C.¹²³⁴,Bloodworth Sally¹²³⁴,Franck Xavier⁵⁶⁷⁸⁹,Whitby Richard J.¹²³⁴

Affiliation:

1. Chemistry, Faculty of Natural and Environmental Sciences

2. University of Southampton

3. Southampton

4. UK

5. Normandie Université

6. COBRA, UMR 6014 & FR 3038

7. Université de Rouen

8. INSA Rouen

9. CNRS

Abstract

Rapid acquisition of kinetic data for thermolysis of 1,3-dioxin-4-ones is demonstrated with a commercial meso-scale flow reactor, using a step-change in flow rate or ‘push-out’ from the flow line.

Funder

GlaxoSmithKline

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Fluid Flow and Transfer Processes,Process Chemistry and Technology,Chemical Engineering (miscellaneous),Chemistry (miscellaneous),Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RE/C5RE00007F

Reference44 articles.

1. Greener Approaches to Organic Synthesis Using Microreactor Technology

2. Optical fiber-based on-line UV/Vis spectroscopic monitoring of chemical reaction kinetics under high pressure in a capillary microreactor

3. Silicon Micromixers with Infrared Detection for Studies of Liquid-Phase Reactions

4. Infrared Spectroscopy for Chemically Specific Sensing in Silicon-Based Microreactors

5. Kinetics study of heterogeneous reactions of ozone with erucic acid using an ATR-IR flow reactor

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