The approach to 4d/4f-polyphosphides-Reference-Cited by-同舟云学术

The approach to 4d/4f-polyphosphides

Published:2015 Issue:12 Volume:6 Page:7179-7184
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Arleth Nicholas¹²³⁴,Gamer Michael T.¹²³⁴,Köppe Ralf¹²³⁴,Pushkarevsky Nikolay A.⁵⁶⁷⁸¹,Konchenko Sergey N.¹²³⁴⁵,Fleischmann Martin¹⁹¹⁰⁴,Bodensteiner Michael¹⁹¹⁰⁴,Scheer Manfred¹⁹¹⁰⁴,Roesky Peter W.¹²³⁴

Affiliation:

1. Institute of Inorganic Chemistry

2. Karlsruhe Institute of Technology

3. 76131 Karlsruhe

4. Germany

5. Nikolaev Institute of Inorganic Chemistry SB RAS

6. Novosibirsk State University

7. 630090 Novosibirsk

8. Russia

9. University of Regensburg

10. 93040 Regensburg

Abstract

The first 4d/4f polyphosphides were obtained from reactions of the divalent metallocenes [Cp*₂Ln(thf)₂] (Ln = Sm, Yb) with [{CpMo(CO)₂}₂(μ,η^2:2-P₂)] or [Cp*Mo(CO)₂(η³-P₃)]. New aggregation of the central phosphorus scaffold in combination with P–P bond formation within the coordination sphere of the transition metal was observed.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC02252E

Reference49 articles.

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