Binuclear metal complexes with a novel hexadentate imidazole derivative for the cleavage of phosphate diesters and biomolecules: distinguishable mechanisms
Author:
Affiliation:
1. School of Chemistry and Environmental Engineering
2. Sichuan University of Science & Engineering
3. Sichuan Zigong 643000
4. P. R. China
5. College of Chemistry and Chemical Engineering
6. Liaocheng University
7. Shandong Liaocheng 252059
Abstract
Oxidative cleavage of phosphate diesters (HPNP, BNPP) is highly faster than the hydrolytic one by binuclear metal complexes with novel imidazole derivative, producing a non-lactone phosphate monoester due to the direct attack of free radicals.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/QI/D1QI00108F
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