Binuclear metal complexes with a novel hexadentate imidazole derivative for the cleavage of phosphate diesters and biomolecules: distinguishable mechanisms

Author:

Shu Jun1234,Yue Jian1234,Qiu Xin1234,Liu Xiaoqiang1234,Ren Wang1234,Li Qianli5674,Li Yulong1234ORCID,Xu Bin1234,Zhang Kaiming1234,Jiang Weidong1234ORCID

Affiliation:

1. School of Chemistry and Environmental Engineering

2. Sichuan University of Science & Engineering

3. Sichuan Zigong 643000

4. P. R. China

5. College of Chemistry and Chemical Engineering

6. Liaocheng University

7. Shandong Liaocheng 252059

Abstract

Oxidative cleavage of phosphate diesters (HPNP, BNPP) is highly faster than the hydrolytic one by binuclear metal complexes with novel imidazole derivative, producing a non-lactone phosphate monoester due to the direct attack of free radicals.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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