Comparison of tetrel bonds in neutral and protonated complexes of pyridineTF3and furanTF3(T = C, Si, and Ge) with NH3-Reference-Cited by-同舟云学术

Comparison of tetrel bonds in neutral and protonated complexes of pyridineTF3and furanTF3(T = C, Si, and Ge) with NH3

Published:2017 Issue:7 Volume:19 Page:5550-5559
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Liu Mingxiu¹²³⁴⁵,Li Qingzhong¹²³⁴⁵^ORCID,Scheiner Steve⁶⁷⁸⁹

Affiliation:

1. The Laboratory of Theoretical and Computational Chemistry

2. School of Chemistry and Chemical Engineering

3. Yantai University

4. Yantai 264005

5. People's Republic of China

6. Department of Chemistry and Biochemistry

7. Utah State University

8. Logan

9. USA

Abstract

Protonation not only changes the primary interaction mode between α/β-furanCF₃/p-PyCF₃and NH₃but also prominently enhances the strength of the Si/Ge⋯N tetrel bond.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CP/C6CP07531B

Reference90 articles.

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2. Tetrel-Bonding Interaction: Rediscovered Supramolecular Force?

3. Tetrel Bonding Interactions

4. Non-covalent sp3carbon bonding with ArCF3is analogous to CH–π interactions

5. Experimental evidence for ‘carbon bonding’ in the solid state from charge density analysis

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