From carbones to carbenes and ylides in the coordination sphere of iridium-Reference-Cited by-同舟云学术

From carbones to carbenes and ylides in the coordination sphere of iridium

Published:2021 Issue:3 Volume:50 Page:954-959
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Li Yinwu¹²³⁴⁵,Maser Leon⁶⁷⁸⁹¹⁰,Alig Lukas⁶⁷⁸⁹,Ke Zhuofeng¹²³⁴⁵^ORCID,Langer Robert⁶⁷⁸⁹¹⁰^ORCID

Affiliation:

1. School of Materials Science & Engineering

2. PCFM Lab

3. Sun Yat-sen University

4. Guangzhou 510275

5. China

6. Institute of Chemistry

7. Faculty of Natural Sciences II

8. Martin-Luther-Universität Halle-Wittenberg

9. Germany

10. Department of Chemistry

Abstract

A carbodiphosphorane-based iridium pincer complex is demonstrated to rearrange in chlorinated organic solvents under cleavage of a P–C-bond to give a chelating phosphine ylide ligand.

Funder

Deutsche Forschungsgemeinschaft

Tip-top Scientific and Technical Innovative Youth Talents of Guangdong Special Support Program

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT03942J

Reference44 articles.

1. Geminal Dianions Stabilized by Main Group Elements

2. Carbodiphosphoranes: The Chemistry of Divalent Carbon(0)

3. Synthesis of an Extremely Bent Acyclic Allene (A “Carbodicarbene”): A Strong Donor Ligand

4. Coordination Chemistry of Ene-1,1-diamines and a Prototype “Carbodicarbene”

5. First and Second Proton Affinities of Carbon Bases

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