Author:
Tonner Ralf,Heydenrych Greta,Frenking Gernot
Subject
Physical and Theoretical Chemistry,Atomic and Molecular Physics, and Optics
Reference114 articles.
1. The proton affinity (PA) is defined as the enthalpy difference between a neutral compound N and the protonated species NH+ at room temperature (298 K). Thermal contributions are included in the PA values. The free energy difference at 298 K, which includes the entropic corrections, are termed gas‐phase basicities.[2].
2. Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update
3. Superbases in the gas phase: Amidine and guanidine derivatives with proton affinities larger than 1000 kj mol−1
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