Photoinduced C–C bond cleavage for the synthesis of 2,4-disubstituted-1-naphthols from indenone derivatives and sulfoxonium ylide-Reference-Cited by-同舟云学术

Photoinduced C–C bond cleavage for the synthesis of 2,4-disubstituted-1-naphthols from indenone derivatives and sulfoxonium ylide

Published:2022 Issue:28 Volume:20 Page:5520-5524
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Khorphueng Prapas¹,Tummatorn Jumreang²³^ORCID,Patumanon Wacharakorn³,Thongsornkleeb Charnsak²³^ORCID,Chonradeenitchakul Sukit²,Ruchirawat Somsak²³

Affiliation:

1. Department of Chemistry, Faculty of Science, Mahanakorn University of Technology, 140 Chueam Samphan Rd, Krathum Rai, Nong Chok, Bangkok, 10530, Thailand

2. Program on Chemical Sciences, Chulabhorn Graduate Institute, Chulabhorn Royal Academy, Center of Excellence on Environmental Health and Toxicology, CHE, Ministry of Education, 54 Kamphaeng Phet 6, Laksi, Bangkok 10210, Thailand

3. Laboratory of Medicinal Chemistry, Chulabhorn Research Institute, 54 Kamphaeng Phet 6, Laksi, Bangkok 10210, Thailand

Abstract

Cyclopropane fused-indanones, generated in situ from indenones and trimethylsulfoxonium chloride, served as precursors under UV-LED (390 nm) irradiation to give 2,4-disubstituted-1-naphthols in up to 81% yield.

Funder

Mahidol University

Ministry of Higher Education, Science, Research and Innovation, Thailand

Ministry of Education

National Research Council of Thailand

Thailand Science Research and Innovation

Chulabhorn Graduate Institute, Chulabhorn Royal Academy

Chulabhorn Royal Academy

Chulabhorn Research Institute

Publisher

Royal Society of Chemistry (RSC)

Subject