Dirhodium(<scp>ii</scp>)-catalyzed regio- and stereoselective cycloisomerization towards 6,5,3-tricyclic skeletons containing vicinal all-carbon quaternary stereocenters-Reference-Cited by-同舟云学术

Dirhodium(ii)-catalyzed regio- and stereoselective cycloisomerization towards 6,5,3-tricyclic skeletons containing vicinal all-carbon quaternary stereocenters

Published:2024 Issue:18 Volume:11 Page:5151-5159
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Xu Zurong¹,Lu Jiajun¹,Jiang Huanfeng¹^ORCID,Wu Rui¹²,Zhu Shifa¹²^ORCID

Affiliation:

1. Key Laboratory of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China

2. School of Chemistry and Chemical Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, China

Abstract

Rh2(ii)-catalyzed regio- and stereoselective cycloisomerization of benzo-fused 1,6-enynes is describled, which enables rapid construction of 6,5,3-tricyclic skeletons with high efficiency and excellent enantioselectivity.

Funder

National Natural Science Foundation of China

Basic and Applied Basic Research Foundation of Guangdong Province

Natural Science Foundation of Guangzhou Municipality

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QO/D4QO00998C

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