Selective carbonylation of benzene to benzaldehyde using a phosphorus–nitrogen PN3P–rhodium(i) complex
Author:
Affiliation:
1. KAUST Catalysis Center and Division of Physical Sciences and Engineering
2. King Abdullah University of Science and Technology
3. Thuwal 23955-6900
4. Saudi Arabia
Abstract
A PN3P–Rh(i) complex realizes the selective carbonylation of benzene to benzaldehyde without irradiation.
Funder
King Abdullah University of Science and Technology
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/QO/C8QO00892B
Reference49 articles.
1. Activation of C−H Bonds by Metal Complexes
2. Rhodium(i)-catalysed decarbonylative direct C–H vinylation and dienylation of arenes
3. Recent advances in positional-selective alkenylations: removable guidance for twofold C–H activation
4. Palladium-Catalyzed Transformations of Alkyl C–H Bonds
5. Oxidative C–H/C–H Coupling Reactions between Two (Hetero)arenes
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