Ligand-centered reactivity of a pseudo-dearomatized phosphorus-nitrogen PN3P* rhodium complex towards molecular oxygen at room temperature-Reference-Cited by-同舟云学术

Ligand-centered reactivity of a pseudo-dearomatized phosphorus-nitrogen PN3P* rhodium complex towards molecular oxygen at room temperature

Published:2020 Issue:10 Volume:7 Page:2017-2022
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Zhou Chunhui¹²³⁴,Munkerup Kristin¹²³⁴,Wang Yuan¹²³⁴,Das Pradip K.¹²³⁴,Chakraborty Priyanka¹²³⁴,Hu Jinsong¹²³⁴,Yao Changguang¹²³⁴,Huang Mei-Hui¹²³⁴,Huang Kuo-Wei¹²³⁴^ORCID

Affiliation:

1. KAUST Catalysis Center & Division of Physical Science and Engineering

2. King Abdullah University of Science and Technology

3. Thuwal 23900-6900

4. Saudi Arabia

Abstract

The pseudo-dearomatized ligand of PN³P*Rh-CO reacts with O₂ to form an α, β-unsaturated carbonyl moiety at room temperature, showcasing an unprecedented ligand-centered reactivity with the oxidation state of Rh(I) remaining untouched.

Funder

King Abdullah University of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/QI/C9QI01605H

Reference41 articles.

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