Self-assembly of a mixed-valence FeII–FeIII tetranuclear star

Author:

Sertphon Darunee1234ORCID,Harding Phimphaka1234ORCID,Murray Keith S.5678ORCID,Moubaraki Boujemaa5678,Chilton Nicholas F.9101112ORCID,Hill Stephen1314151617,Marbey Jonathan1314151617,Adams Harry18192012,Davies Casey G.21222324,Jameson Guy N. L.212223245ORCID,Harding David J.1234ORCID

Affiliation:

1. Functional Materials and Nanotechnology Centre of Excellence

2. Walailak University

3. Thasala

4. Thailand

5. School of Chemistry

6. Monash University

7. Clayton

8. Australia

9. School of Chemistry and Photon Science Institute

10. The University of Manchester

11. Manchester M13 9PL

12. UK

13. Florida State University

14. Department of Physics

15. Tallahassee

16. USA

17. National High Magnetic Field Laboratory

18. Department of Chemistry

19. University of Sheffield

20. Sheffield

21. Department of Chemistry & MacDiarmid Institute for Advanced Materials and Nanotechnology

22. University of Otago

23. Dunedin

24. New Zealand

Abstract

A self-assembled mixed-valence FeII–FeIII tetranuclear star is reported that shows ferromagnetic coupling, field-induced single molecule magnetism and strong magnetic anisotropy at the peripheral FeII centres.

Funder

Thailand Research Fund

Australian Research Council

National Science Foundation

Ramsay Memorial Fellowships Trust, University College London

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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