Self-assembly of a trigonal bipyramidal architecture with stabilisation of iron in three spin states

Author:

Taylor Lauren L. K.1ORCID,Vitorica-Yrezabal Iñigo J.1,Borilović Ivana12,Tuna Floriana12ORCID,Riddell Imogen A.1ORCID

Affiliation:

1. Department of Chemistry, University of Manchester, Oxford Road, Manchester, M13 9PL, UK

2. Photon Science Institute, University of Manchester, Oxford Road, Manchester, M13 9PL, UK

Abstract

Self-assembly of a trigonal bipyramidal architecture with a central mixed oxidation state star from a heterotopic ligand and a single metal salt. Characterisation confirms incorporation of iron as low-spin iron(ii), high-spin iron(ii) and iron(iii).

Funder

Diamond Light Source

Royal Society

Engineering and Physical Sciences Research Council

Leverhulme Trust

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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