Soluble and processable thermoplastic hybrid polyimides containing POSS in main chains-Reference-Cited by-同舟云学术

Soluble and processable thermoplastic hybrid polyimides containing POSS in main chains

Published:2022 Issue:35 Volume:13 Page:5145-5151
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Kamitani Tasuku¹,Imoto Hiroaki¹,Naka Kensuke¹²^ORCID

Affiliation:

1. Faculty of Molecular Chemistry and Engineering, Kyoto Institute of Technology, Goshokaido-cho, Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan

2. Materials Innovation Lab, Kyoto Institute of Technology, Goshokaido-cho, Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan

Abstract

The combination of 3,13-bis(3-aminopropyl)-double-decker-shaped-silsesquioxane and a fluorinated dianhydride produces a flexible polyimide with a low Tg, high heat resistance, and excellent solvent solubility. The fluorinated dianhydride loosened the interchain packing to suppress CT interactions, leading to the formation of a colorless polyimide.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2022/PY/D2PY00980C

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3. Synthesis of Wholly Alicyclic Polyimides from N-Silylated Alicyclic Diamines and Alicyclic Dianhydrides