Multifunctional Zn(ii)–Yb(iii) complex enantiomers showing second-harmonic generation, near-infrared luminescence, single-molecule magnet behaviour and proton conduction

Author:

Zhu Shui-Dong1234,Hu Jun-Jie1234,Dong Lu1534,Wen He-Rui1234ORCID,Liu Sui-Jun1234ORCID,Lu Ying-Bing1534,Liu Cai-Ming678910ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering

2. Jiangxi University of Science and Technology

3. Ganzhou 341000

4. P. R. China

5. Gannan Normal University

6. Beijing National Laboratory for Molecular Sciences

7. Center for Molecular Science

8. Key Laboratory of Organic Solids

9. Institute of Chemistry

10. Chinese Academy of Sciences

Abstract

A new pair of Zn(ii)–Yb(iii) enantiomers with trinuclear structures were synthesized by using a chiral amine-phenol ligand, and they show unprecedented five-functionality by association of SMM, luminescent and proton conductive properties.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Jiangxi Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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