Elevating the Performance of Heterometallic 3d/4f SMMs: The Role of Diamagnetic Co<sup>III</sup> and Zn<sup>II</sup> Ions in Magnetization Dynamics-Reference-Cited by-同舟云学术

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Elevating the Performance of Heterometallic 3d/4f SMMs: The Role of Diamagnetic Co^III and Zn^II Ions in Magnetization Dynamics

Published:2024-08-19 Issue: Volume: Page:
ISSN:1439-4235
Container-title:ChemPhysChem
language:en
Short-container-title:ChemPhysChem

Author:

Vipanchi ¹^ORCID,Vignesh Kuduva R.¹^ORCID,Armenis Alexandros S.²,Alexandropoulos Dimitris I.²^ORCID,Stamatatos Theocharis C.²^ORCID

Affiliation:

1. Department of Chemical Sciences Indian Institute of Science Education and Research (IISER) Mohali Sector-81, Knowledge city, S.A.S. Nagar Mohali, Punjab 140306 India

2. Department of Chemistry University of Patras 265 04 Patras Greece

Abstract

AbstractRecent advances in the synthesis of 3d/4f Single‐Molecule Magnets (SMMs) have revealed the effective role of incorporating diamagnetic CoIII or ZnII ions to enhance the magnetic properties of LnIII ions. This concept highlights notable examples of CoIII/LnIII and ZnII/LnIII SMMs documented in the recent literature, illustrating how the selection of various peripheral and/or bridging ligands can modulate the magnetic anisotropy of 4f metal ions, thereby increasing their energy barriers.

Funder

Science and Engineering Research Board

Publisher

Wiley

Reference72 articles.

2. Magnetic bistability in a metal-ion cluster

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5. D. Gatteschi R. Sessoli J. Villain Oxford University Press Oxford UK2006;

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