trans-Chloridobis[(Z)-1-imino-1-methoxyethane-κN](triphenylphosphane-κP)platinum(II) chloride monohydrate-Reference-Cited by-同舟云学术

trans-Chloridobis[(Z)-1-imino-1-methoxyethane-κN](triphenylphosphane-κP)platinum(II) chloride monohydrate

Published:2012-10-18 Issue:11 Volume:68 Page:m300-m302
ISSN:0108-2701
Container-title:Acta Crystallographica Section C Crystal Structure Communications
language:
Short-container-title:Acta Crystallogr C

Author:

Giardina-Papa Daniela,Intini Francesco Paolo,Natile Giovanni,Pacifico Concetta

Abstract

The title compound, [PtCl(C3H7NO)2(C18H15P)]Cl·H2O ortrans-[PtCl{Z-HN=C(Me)OMe}2(PPh3)]Cl·H2O, crystallizes from an acetone solution of isomerictrans-[PtCl{E-HN=C(Me)OMe}2(PPh3)]Cl. The two HN=C(Me)OMe ligands show typical π-bond delocalization over the N—C—O group [Cini, Caputo, Intini & Natile (1995).Inorg. Chem.34, 1130–1137] and have the unprecedentedZ–anticonfiguration. The relative orientation of the imino ether ligands is head-to-tail.

Publisher

International Union of Crystallography (IUCr)

Subject

General Biochemistry, Genetics and Molecular Biology,General Medicine

Link

http://journals.iucr.org/c/issues/2012/11/00/eg3099/eg3099.pdf

Reference28 articles.

1. Model platinum nucleobase and nucleoside complexes and antitumor activity: X-ray crystal structure of [PtIV(trans-1R,2R-diaminocyclohexane)trans-(acetate)2(9-ethylguanine)Cl]NO3·H2O

2. The structure ofcis-dichloro-bis-(triphenylphosphine)platinum(II); a product in the reaction ofcis-[PtCl2(CO)(PPh3)] with tin (II) chloride

3. Bruker (2004). COSMO, APEX2, BIS and SAINT-IRIX. Bruker AXS Inc., Madison, Wisconsin, USA.

4. SIR2004: an improved tool for crystal structure determination and refinement

5. Mechanistic and Stereochemical Investigation of Imino Ethers Formed by Alcoholysis of Coordinated Nitriles: X-ray Crystal Structures of cis- and trans-Bis(1-imino-1-methoxyethane)dichloroplatinum(II)

Cited by 3 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Organophosphine ligands in PtPX2Y and PtPXYZ complexes; structural aspects;Transition Metal Chemistry;2017-05-28

2. Small-molecule activation at Au(iii): metallacycle construction from ethylene, water, and acetonitrile;Dalton Transactions;2016

3. Isomerization of Platinum-Coordinated Iminoethers Induced by Spectator Ligands: Stabilization of the Z anti Configuration;Inorganic Chemistry;2013-11-04