Annular beam high-intensity X-ray diffraction based on an ellipsoidal single-bounce monocapillary

Abstract

This short communication presents a study of the use of an annular X-ray beam produced by an ellipsoidal single-bounce monocapillary (ESBC) to perform focal construct geometry (FCG) high-intensity angular-dispersive X-ray diffraction (ADXRD) in transmission mode. The ESBC optic effectively focused a large focal spot X-ray source into a smaller focal spot and produced a narrowed X-ray ring in the far-field pattern when combined with a beam stop. A CCD imaging detector was linearly translated along the principal axis of the ESBC-FCG and obtained the corresponding sequential images of diffraction concentric circular caustics and convergence points, which were formed by the constructive interference of a continuous set of Debye cones arising from the annular interrogation volume. Pixels from the central region of an approximately 0.6 mm2 area were interrogated on each sequential image; as a result, a one-dimensional diffractogram of an aluminium oxide sample was revealed. The presented ESBC-FCG ADXRD technique shows potential for increasing the diffracted intensity and streamlining the operation of crystallographic analysis.