Tris(benzyldiphenylphosphane-κP)(nitrato-κO)silver(I)

Author:

Potgieter Kariska,Malan Frederick P.,Alimi Oyekunle Azeez,Meijboom Reinout

Abstract

The molecular structure of the title complex, [Ag(NO3)(C19H17P)3], exhibits a severely distorted tetrahedral coordination environment around the central AgI atom, comprising one O and three P atoms. Apart from a primary Ag—O coordination of the nitrato ligand of 2.667 (3) Å, a second (weaker) secondary interaction of the nitrato ligand via the other O atom of 3.118 (4) Å is observed. The compound crystallizes with a complete molecule in the asymmetric unit. Weak C—H...O interactions consolidate the packing.

Funder

National Research Foundation

Publisher

International Union of Crystallography (IUCr)

Subject

Organic Chemistry,Inorganic Chemistry,Analytical Chemistry

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