Author:
Sathya Udhayasuriyan,Nirmal Ram Jeyaraman Selvaraj,Gomathi Sundaramoorthy,Jegan Jennifer Samson,Abdul Razak Ibrahim
Abstract
The asymmetric unit of the title coordination polymer [Zn(C9H6NO2)2(C10H8N4)]
n
, consists of one ZnII cation, one bidentate 1H-indole-5-carboxylate (I5C) anion and half of a 4,4′-azobipyridine (Abpy) neutral ligand. In the coordination polyhedron, the ZnII ion adopts a distorted octahedral geometry. The coordination polymer is stabilized by a combination of N—H...O and C—H...π interactions, which leads to the formation of wave-like two-dimensional coordination polymeric layers.
Publisher
International Union of Crystallography (IUCr)
Subject
Rehabilitation,Physical Therapy, Sports Therapy and Rehabilitation,General Medicine
Reference14 articles.
1. Bruker (2016). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
2. Cason, C. J. (2004). POV-RAY for Windows. Persistence of Vision, Raytracer Pty. Ltd, Victoria, Australia. URL: http://www.povray. org
3. A twofold interpenetrating two-dimensional zinc(II) coordination polymer: synthesis, crystal structure and physical properties
4. A twofold interpenetrating three-dimensional zinc–organic framework built from naphthalene-1,4-dicarboxylate and 4,4′-bipyridine ligands
5. A new two-dimensional ZnIIcoordination polymer constructed by a multidentate N-heterocyclic ligand and 5-carboxybenzene-1,3-dicarboxylate