Author:
Chen Ning-Ning,Zhang Chen,Tao Jian-Qing
Abstract
A novel twofold interpenetrating two-dimensional (2D) ZnII coordination framework, poly[[(μ-1,3-bis(2-methyl-1H-imidazol-1-yl)benzene-κ2
N
3:N
3)(μ-naphthalene-2,6-dicarboxylato-κ2
O
2:O
6)zinc(II)] dimethylformamide monosolvate], {[Zn(C12H6O4)(C14H14N4)]·C3H7NO}
n
or {[Zn(1,3-BMIB)(NDC)]·DMF}
n
(I), where H2NDC is naphthalene-2,6-dicarboxylic acid, 1,3-BMIB is 1,3-bis(2-methyl-1H-imidazol-1-yl)benzene and DMF is dimethylformamide, was prepared and characterized through IR spectroscopy, elemental analysis, thermal analysis and single-crystal X-ray diffraction. Single-crystal X-ray diffraction analysis revealed that (I) exhibits an unusual twofold interpenetrating 2D network. In addition, it displays strong fluorescence emissions and a high photocatalytic activity for the degradation of Rhodamine B (RhB) under UV-light irradiation.
Publisher
International Union of Crystallography (IUCr)
Subject
Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry,Condensed Matter Physics
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