Author:
Pavlyuk Volodymyr,Dmytriv Grygoriy,Szyrej Malgorzata,Levkovets Sergii,Parasyuk Oleh
Abstract
A novel quaternary mixed halogenide, Tl5Hg2Br5I4, was synthesized by fusion of thallium bromide and mercury iodide in a 5:2 molar ratio. The crystal structure of Tl5Hg2Br5I4represents a new series of composite structures described by the general formulanTlBr*mTl2[HgBr2I2]; in this case,n= 4 andm= 8. Electronic structure calculations indicate that the title compound is a semiconductor.
Publisher
International Union of Crystallography (IUCr)
Subject
Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry,Condensed Matter Physics
Cited by
2 articles.
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