Author:
Mouas Nardjes,Merazig Hocine,Daran Jean-Claude,Manoury Eric
Abstract
2-(Diphenylthiophosphino)dimethylaminomethylferrocene is a key intermediate in the synthesis of various ferrocenyl ligands. During one such synthesis, the title compound, [Fe(C5H5)(C20H22NPS)](C12H10PS2), was isolated as a by-product. It is built up by association of (2-(diphenylphosphino)ferrocenyl)methyl)dimethylammonium cations and diphenylphosphino dithioate anions. N—H...S, C—H...S and C—H...π interactions link the anions and cations. Each anion–cation pair is linked two by two through C—H...π interactions, forming pseudo dimers.
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Cited by
2 articles.
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