Abstract
The title compounds, C13H18O3Si (1) and C18H20O3Si (2), represent functionalizable dihydrofuranylsilanes, which permit substitution by a variety of nucleophiles. The crystal structures of 1 and 2 display weak intermolecular C—H...O hydrogen-bonding interactions (quantified by Hirshfeld surface analysis), leading to a two-dimensional supramolecular network for 1 and a one-dimensional supramolecular network for 2. The crystal structures of 1 and 2 were refined both on the basis of the independent atom model (IAM) and the Hirshfeld atom refinement (HAR) approach, and the results are comparatively discussed.
Funder
Fonds der Chemischen Industrie
Studienstiftung des Deutschen Volkes
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Reference28 articles.
1. Tables of bond lengths determined by X-ray and neutron diffraction. Part 1. Bond lengths in organic compounds
2. Bruker (2016). SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
3. Bruker (2018). APEX2. Bruker AXS Inc., Madison, Wisconsin, USA.
4. Hirshfeld atom refinement
Cited by
3 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献