Abstract
Excellent fluorescence properties are exhibited by d
10 metal compounds. The novel three-dimensional ZnII coordination framework, poly[[{μ2-bis[4-(2-methyl-1H-imidazol-1-yl)phenyl] ether-κ2
N
3:N
3′}(μ2-furan-2,5-dicarboxylato-κ2
O
2:O
5)zinc(II)] 1.76-hydrate], {[Zn(C6H2O5)(C20H18N4O)]·1.76H2O}
n
, has been prepared and characterized using IR spectroscopy, elemental analysis and single-crystal X-ray diffraction. The crystal structure analysis revealed that the compound exhibits a novel fourfold interpenetrating diamond-like network. This polymer also displays a strong fluorescence emission in the solid state at room temperature.
Publisher
International Union of Crystallography (IUCr)
Subject
Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry,Condensed Matter Physics
Reference24 articles.
1. Synthesis, structure, and photoluminescent behaviour of molecular lanthanide–2-thiophenecarboxylate–2,2′:6′,2′′-terpyridine materials
2. Design, Synthesis, and Antibacterial Assessment of Silver(I)-Based Coordination Polymers with Variable Counterions and Unprecedented Structures by the Tuning Spacer Length and Binding Mode of Flexible Bis(imidazole-2-thiones) Ligands
3. Interpenetrating metal–organic and inorganic 3D networks: a computer-aided systematic investigation. Part I. Analysis of the Cambridge structural database
4. Blatov, V. A. & Shevchenko, A. P. (2006). TOPOS. Version 4.0. Samara State University, Samara, Russia.
5. Brandenburg, K. & Putz, H. (2005). DIAMOND. Crystal Impact GbR, Bonn, Germany.
Cited by
2 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献