Synthesis, structure, and photoluminescent behaviour of molecular lanthanide–2-thiophenecarboxylate–2,2′:6′,2′′-terpyridine materials

Author:

Batrice Rami J.1234ORCID,Ridenour J. August1534ORCID,Ayscue III R. Lee1234ORCID,Bertke Jeffery A.1234ORCID,Knope Karah E.1234ORCID

Affiliation:

1. Department of Chemistry

2. Georgetown University

3. Washington

4. USA

5. The George Washington University

Abstract

A lanthanide series incorporating 2-thiophenecarboxylate and terpyridine is presented. Four structure types are observed with differences in the coordination number and nuclearity of the complexes attributed to the effects of the lanthanide contraction.

Funder

U.S. Department of Defense

Henry Luce Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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4. Taking advantage of luminescent lanthanide ions

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