Revealing a double-inversion mechanism for the F−+CH3Cl SN2 reaction
Author:
Publisher
Springer Science and Business Media LLC
Subject
General Physics and Astronomy,General Biochemistry, Genetics and Molecular Biology,General Chemistry
Link
http://www.nature.com/articles/ncomms6972.pdf
Reference22 articles.
1. Chabinyc, M. L., Craig, S. L., Regan, C. K. & Brauman, J. I. Gas-phase ionic reactions: dynamics and mechanism of nucleophilic displacements. Science 279, 1882–1886 (1998).
2. Sun, L., Song, K. & Hase, W. L. A SN2 reaction that avoids its deep potential energy minimum. Science 296, 875–878 (2002).
3. Gonzales, J. M. et al. Definitive ab initio studies of model SN2 reactions CH3X+F− (X=F, Cl, CN, OH, SH, NH2, PH2). Chem. Eur. J. 9, 2173–2192 (2003).
4. Mikosch, J. et al. Imaging nucleophilic substitution dynamics. Science 319, 183–186 (2008).
5. Brauman, J. I. Not so simple. Science 319, 168–168 (2008).
Cited by 134 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. Vibrational mode-specificity in the dynamics of the OH− + CH3I multi-channel reaction;The Journal of Chemical Physics;2024-01-24
2. A facile synthesis of precursor for the σ‐1 receptor PET radioligand [18F]FTC‐146 and its radiofluorination;Journal of Labelled Compounds and Radiopharmaceuticals;2024-01-03
3. Computational Insights into SN2 and Proton Transfer Reactions of CH3O− with NH2Y and CH3Y;ChemPhysChem;2023-11-29
4. Accurate fundamental invariant-neural network representation of ab initio potential energy surfaces;National Science Review;2023-11-06
5. Alternating Stereospecificity upon Central‐Atom Change: Dynamics of the F−+PH2Cl SN2 Reaction Compared to its C‐ and N‐Centered Analogues;Chemistry – A European Journal;2023-09-12
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3