Ultraviolet photolysis of H2S and its implications for SH radical production in the interstellar medium

Author:

Zhou Jiami,Zhao Yarui,Hansen Christopher S.,Yang Jiayue,Chang YaoORCID,Yu Yong,Cheng Gongkui,Chen Zhichao,He Zhigang,Yu Shengrui,Ding Hongbin,Zhang Weiqing,Wu GuorongORCID,Dai Dongxu,Western Colin M.ORCID,Ashfold Michael N. R.ORCID,Yuan KaijunORCID,Yang XuemingORCID

Abstract

AbstractHydrogen sulfide radicals in the ground state, SH(X), and hydrogen disulfide molecules, H2S, are both detected in the interstellar medium, but the returned SH(X)/H2S abundance ratios imply a depletion of the former relative to that predicted by current models (which assume that photon absorption by H2S at energies below the ionization limit results in H + SH photoproducts). Here we report that translational spectroscopy measurements of the H atoms and S(1D) atoms formed by photolysis of jet-cooled H2S molecules at many wavelengths in the range 122 ≤ λ ≤155 nm offer a rationale for this apparent depletion; the quantum yield for forming SH(X) products, Γ, decreases from unity (at the longest excitation wavelengths) to zero at short wavelengths. Convoluting the wavelength dependences of Γ, the H2S parent absorption and the interstellar radiation field implies that only ~26% of photoexcitation events result in SH(X) products. The findings suggest a need to revise the relevant astrochemical models.

Funder

the Strategic Priority Research Program of the Chinese Academy of Sciences

Publisher

Springer Science and Business Media LLC

Subject

General Physics and Astronomy,General Biochemistry, Genetics and Molecular Biology,General Chemistry

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