A double bond with weak σ- and strong π-interactions is still a double bond
Author:
Publisher
Springer Science and Business Media LLC
Subject
General Physics and Astronomy,General Biochemistry, Genetics and Molecular Biology,General Chemistry
Link
http://www.nature.com/articles/s41467-021-24238-x.pdf
Reference22 articles.
1. Abe, M. & Akisaka, R. Is π-single bonding (C–π–C) possible? A challenge in organic chemistry. Chem. Lett. 46, 1586–1592 (2017).
2. Akisaka, R. & Abe, M. Bulky Substituent effect on reactivity of localized singlet cyclopentane-1,3-diyls with π-single bonding (C-π-C) character. Chem. Asian J. 14, 4223–4228 (2019).
3. Nakagaki, T., Sakai, T., Mizuta, T., Fujiwara, Y. & Abe, M. Kinetic stabilization and reactivity of π single-bonded species: effect of the alkoxy group on the lifetime of singlet 2,2-Dialkoxy-1,3-diphenyloctahydropentalene-1,3-diyls. Chem. Eur. J. 19, 10395–10404 (2013).
4. Kyushin, S. et al. Silicon–silicon π single bond. Nat. Commun. 11, 4009 (2020).
5. Landis, C. R. & Weinhold, F. The NBO View of Chemical Bonding. in The Chemical Bond 91–120 (John Wiley & Sons, Ltd, 2014). https://doi.org/10.1002/9783527664696.ch3.
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