Four-membered heterocyclic molecules featuring boron and heavy group 14 elements that exhibit both σ-aromatic and π-aromatic properties: a new synthetic target-Reference-Cited by-同舟云学术

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Four-membered heterocyclic molecules featuring boron and heavy group 14 elements that exhibit both σ-aromatic and π-aromatic properties: a new synthetic target

Published:2024 Issue:35 Volume:53 Page:14866-14874
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zhang Zheng-Feng¹,So Cheuk-Wai²^ORCID,Su Ming-Der¹³^ORCID

Affiliation:

1. Department of Applied Chemistry, National Chiayi University, Chiayi 60004, Taiwan

2. School of Chemistry, Chemical Engineering and Biotechnology, Nanyang Technological University, 637371, Singapore

3. Department of Medicinal and Applied Chemistry, Kaohsiung Medical University, Kaohsiung 80708, Taiwan

Abstract

Theoretical findings demonstrate that the inorganic four-membered heterocyclic neutral molecules (B2G14G14′) display both σ-aromaticity and π-aromaticity.

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT02002B

Reference28 articles.

1. Diradicals

2. A Dimer of Silaisonitrile with Two-Coordinate Silicon Atoms

3. Group 15 biradicals: synthesis and reactivity of cyclobutane-1,3-diyl and cyclopentane-1,3-diyl analogues

4. Exotic Structures of Si2B2H4

5. Singlet Diradicals: from Transition States to Crystalline Compounds

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