A topological transition by confinement of a phase separating system with radial quenching

Abstract

Abstract Physicochemical systems are strongly modified by spatial confinement; the effect is more pronounced the stronger the confinement is, making its influence particularly important nanotechnology applications. For example, a critical point of a phase transition is shifted by a finite size effect; structure can be changed through wetting to a container wall. Recently, it has been shown that pattern formation during a phase separation is changed when a system is heterogeneously quenched instead of homogeneously. Flux becomes anisotropic due to a heterogeneous temperature field; this suggests that the mechanism behind heterogeneous quenching is different from that of homogeneous quenching. Here, we numerically study the confinement effect for heterogeneously quenched systems. We find that the pattern formed by the phase separation undergoes a topological change with stronger confinement i.e. when the height of a simulation box is varied, transforming from a one-dimensional layered pattern to a two-dimensional pattern. We show that the transition is induced by suppression of the heterogeneous flux by spatial confinement. Systems with heterogeneous flux are ubiquitous; the effect is expected to be relevant to a wide variety of non-equilibrium processes under the action of spatial confinement.