Tandem intermolecular [4 + 2] cycloadditions are catalysed by glycosylated enzymes for natural product biosynthesis
Author:
Publisher
Springer Science and Business Media LLC
Subject
General Chemical Engineering,General Chemistry
Link
https://www.nature.com/articles/s41557-023-01260-8.pdf
Reference56 articles.
1. Jeon, B.-s, Wang, S.-A., Ruszczycky, M. W. & Liu, H.-W. Natural [4 + 2]-cyclases. Chem. Rev. 117, 5367–5388 (2017).
2. Dan, Q. et al. Fungal indole alkaloid biogenesis through evolution of a bifunctional reductase/Diels–Alderase. Nat. Chem. 11, 972–980 (2019).
3. Kim, H. J., Ruszczycky, M. W., Choi, S.-H., Liu, Y.-N. & Liu, H.-W. Enzyme-catalysed [4 + 2] cycloaddition is a key step in the biosynthesis of spinosyn A. Nature 473, 109–112 (2011).
4. Little, R. et al. Unexpected enzyme-catalysed [4 + 2] cycloaddition and rearrangement in polyether antibiotic biosynthesis. Nat. Catal. 2, 1045–1054 (2019).
5. Ohashi, M. et al. An enzymatic Alder-ene reaction. Nature 586, 64–69 (2020).
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