Abstract
AbstractThe surface tension of dispersions presents many types of behaviours. Although some models, based on classical surface thermodynamics, allow partial interpretation, fundamental understanding is still lacking. This work develops a single analytical physics-based formulation experimentally validated for the surface tension of various pure nanoparticle dispersions, explaining the underlying mechanisms. Against common belief, surface tension increase of dispersions appears not to occur at low but rather at intermediate surface coverage, owed by the relatively large size of nanoparticles with respect to the fluid molecules. Surprisingly, the closed-form model shows that the main responsible mechanism for the various surface tension behaviours is not the surface chemical potential of adsorbed nanoparticles, but rather that of non-occupied sites, triggered and delicately controlled by the nanoparticles ‘at a distance’, introducing the concept of the ‘non-occupancy’ effect. The model finally invites reconsidering surface thermodynamics of dispersions and provides for criteria that allow in a succinct manner to quantitatively classify the various surface tension behaviours.
Funder
European Space Agency
Federaal Wetenschapsbeleid
Publisher
Springer Science and Business Media LLC
Subject
Space and Planetary Science,Physics and Astronomy (miscellaneous),Agricultural and Biological Sciences (miscellaneous),Biochemistry, Genetics and Molecular Biology (miscellaneous),Materials Science (miscellaneous),Medicine (miscellaneous)
Cited by
1 articles.
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