Dramatically Accelerated Selective Oxygen-Atom Transfer by a Nonheme Iron(IV)-Oxo Complex: Tuning of the First and Second Coordination Spheres-Reference-Cited by-同舟云学术

Dramatically Accelerated Selective Oxygen-Atom Transfer by a Nonheme Iron(IV)-Oxo Complex: Tuning of the First and Second Coordination Spheres

Published:2014-02-10 Issue:7 Volume:136 Page:2699-2702
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Widger Leland R.¹,Davies Casey G.²,Yang Tzuhsiung¹,Siegler Maxime A.¹,Troeppner Oliver³,Jameson Guy N. L.²,Ivanović-Burmazović Ivana³,Goldberg David P.¹

Affiliation:

1. Department of Chemistry, The Johns Hopkins University, 3400 North Charles Street, Baltimore, Maryland 21218, United States

2. Department of Chemistry & MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Otago, P.O. Box 56, Dunedin 9054, New Zealand

3. Department of Chemistry and Pharmacy, University of Erlangen-Nürnberg, 91058 Erlangen, Germany

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja410240c

Reference37 articles.

1. High-valent nonheme iron-oxo complexes: Synthesis, structure, and spectroscopy

2. Role of the Secondary Coordination Sphere in Metal-Mediated Dioxygen Activation

3. Intrinsic properties and reactivities of mononuclear nonheme iron–oxygen complexes bearing the tetramethylcyclam ligand

4. Sulfur oxygenation in biomimetic non-heme iron–thiolate complexes

5. Addition of Dioxygen to an N4S(thiolate) Iron(II) Cysteine Dioxygenase Model Gives a Structurally Characterized Sulfinato–Iron(II) Complex

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