The First Observation and Full Characterization of All Atropisomers and Their Allowed Interconversions in an Octahedral Bis(bipyridine)ruthenium(II) Complex with Two Lopsided Bicyclic Ligands, as Studied by 2D NMR Techniques at Variable Temperature-Reference-Cited by-同舟云学术

The First Observation and Full Characterization of All Atropisomers and Their Allowed Interconversions in an Octahedral Bis(bipyridine)ruthenium(II) Complex with Two Lopsided Bicyclic Ligands, as Studied by 2D NMR Techniques at Variable Temperature

Published:1999-05-22 Issue:12 Volume:38 Page:2762-2763
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Velders Aldrik H.¹,Hotze Anna C. G.¹,Haasnoot Jaap G.¹,Reedijk Jan¹

Affiliation:

1. Leiden Institute of Chemistry, Gorlaeus Laboratories, Leiden University, PO Box 9502, 2300 RA Leiden, The Netherlands

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic990053l

Reference17 articles.

1. Reedijk, J.Chem.Commun.1996, 801 and references therein.

2. Effects of Six-Membered-Ring Conformation on the Rotamer Distribution and Rate of Atropisomerization in Platinum(II)−Guanine Compounds: 2,4-Bis(methylamino)pentane Complexes

3. Crystal and molecular structure of cis-[Pt(NH3)2[d(pGpG)]], the principal adduct formed by cis-diamminedichloroplatinum(II) with DNA

4. Stereochemically controlled ligands influence atropisomerization of platinum(II) nucleotide complexes. Evidence for head-to-head and stable .LAMBDA. head-to-tail atropisomers

5. Complexes of lopsided N-donor heterocyclic bioligands: Has the electrostatic effect of the N2CH proton been overlooked in metallobiochemistry?

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