Mechanistic Investigations on E–N Bond-Breaking and Ring Expansion for N-Heterocyclic Carbene Analogues Containing the Group 14 Elements (E)
Author:
Affiliation:
1. Department of Applied Chemistry, National Chiayi University, Chiayi 60004, Taiwan
2. Department of Medicinal and Applied Chemistry, Kaohsiung Medical University, Kaohsiung 80708, Taiwan
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic500182f
Reference46 articles.
1. CN Bond Cleavage and Ring Expansion of N-Heterocyclic Carbenes using Hydrosilanes
2. Carbene-Bound Borane and Silane Adducts: A Comprehensive DFT Study on Their Stability and Propensity for Hydride-Mediated Ring Expansion
3. Comparison of the Mechanism of Borane, Silane, and Beryllium Hydride Ring Insertion into N-Heterocyclic Carbene C–N Bonds: A Computational Study
4. A theoretical study on the ring expansion of NHCs by silanes
5. Mechanism and Regioselectivity of C–N Bond Cleavage and Ring Expansion of N-Heterocyclic Carbenes
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