Catalytic Reduction of cis-Dimethyldiazene by the [MoFe3S4]3+ Clusters. The Four-Electron Reduction of a NN Bond by a Nitrogenase-Relevant Cluster and Implications for the Function of Nitrogenase

Author:

Malinak Steven M.1,Simeonov Anton M.1,Mosier Patrick E.1,McKenna Charles E.1,Coucouvanis Dimitri1

Affiliation:

1. Contribution from the Department of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109-1055, and Department of Chemistry, The University of Southern California, Los Angeles, California 90089-0744

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference38 articles.

1. Present Address:  Department of Macromolecular Science, Case Western Reserve University, Cleveland OH 44106-7202.

2. ACS Symposium Series 535;Molybdenum Enzymes,1993

3. Dalton perspectives. Metals in the nitrogenases

4. Nitrogenase and biological nitrogen fixation

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