Highly Activated Terminal Carbon Monoxide Ligand in an Iron–Sulfur Cluster Model of FeMco with Intermediate Local Spin State at Fe
Author:
Affiliation:
1. Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, United States
2. Max Planck Institute for Chemical Energy Conversion, Stiftstraße 34-36, 45470 Mülheim an der Ruhr, Germany
Funder
Max-Planck-Gesellschaft
Alexander von Humboldt-Stiftung
National Institute of General Medical Sciences
Publisher
American Chemical Society (ACS)
Link
https://pubs.acs.org/doi/pdf/10.1021/jacs.3c12025
Reference58 articles.
1. Nitrogenase FeMoco investigated by spatially resolved anomalous dispersion refinement
2. The structure of vanadium nitrogenase reveals an unusual bridging ligand
3. Extending the Carbon Chain: Hydrocarbon Formation Catalyzed by Vanadium/Molybdenum Nitrogenases
4. Catalytic Reduction of CN−, CO, and CO2by Nitrogenase Cofactors in Lanthanide-Driven Reactions
5. CO Binding to the FeMo Cofactor of CO-Inhibited Nitrogenase: 13CO and 1H Q-Band ENDOR Investigation
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