Multi-phosphine-chelated iron-carbide clusters via redox-promoted ligand exchange on an inert hexa-iron-carbide carbonyl cluster, [Fe6(μ6-C)(μ2-CO)4(CO)12]2−-Reference-Cited by-同舟云学术

Multi-phosphine-chelated iron-carbide clusters via redox-promoted ligand exchange on an inert hexa-iron-carbide carbonyl cluster, [Fe₆(μ₆-C)(μ₂-CO)₄(CO)₁₂]²⁻

Published:2024 Issue:29 Volume:15 Page:11455-11471
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Cobb Caitlyn R.¹^ORCID,Ngo Ren K.¹^ORCID,Dick Emily J.¹^ORCID,Lynch Vincent M.¹,Rose Michael J.¹^ORCID

Affiliation:

1. Department of Chemistry, The University of Texas at Austin, Austin, TX 78712, USA

Abstract

We report the reactivity, structures and spectroscopic characterization of reactions of phosphine-based ligands (mono-, di- and tri-dentate) with iron-carbide-carbonyl clusters.

Funder

Welch Foundation

Division of Chemistry

National Science Foundation Graduate Research Fellowship Program

University of Texas at Austin

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC01370K

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