Unusual Mechanism for the Reaction of a Niobocene Hydride Complex with Activated Alkynes. Experimental and DFT Studies-Reference-Cited by-同舟云学术

Unusual Mechanism for the Reaction of a Niobocene Hydride Complex with Activated Alkynes. Experimental and DFT Studies

Published:2015-01-13 Issue:11 Volume:34 Page:2695-2698
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Antiñolo Antonio¹,Garcı́a-Yuste Santiago¹,Otero Antonio¹,Espinosa Arturo²

Affiliation:

1. Dpto. de Quı́mica Inorgánica, Orgánica y Bioquı́mica, Facultad de Ciencias y Tecnologı́as Quı́micas, Universidad de Castilla La Mancha, 13071 Ciudad Real, Spain

2. Departamento de Quı́mica Orgánica, Facultad de Ciencias, Universidad de Murcia, Campus de Espinardo, 30100 Espinardo, Murcia, Spain

Funder

Ministerio de Economía y Competitividad

European Cooperation in Science and Technology

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om5010989

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3. Mechanistic investigation of olefin insertion into the rhodium-hydrogen bond

4. η-Benzenebis(trimethylphosphine)iron as a precursor to [Fe(η-C5R5)(PMe3)2](R = H or Me) derivatives: the equilibrium [Fe](PMe3)Et ⇌[Fe](η-C2H4)H + PMe3, where [Fe]= Fe(η-C5Me5)(PMe3)

5. Kinetics and mechanism of the insertion of olefins into transition metal-hydride bonds

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4. Substituent-regulated mechanism on reaction Cp2NbH3 (Cp = η5-C5H5) with RCCR (R = COOMe and Me);Dalton Transactions;2020

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