W2Cl4(NR2)2(PR‘3)2 Molecules. 8. Synthesis and Structural Characterization of Both Cis Isomers of Stoichiometry W2Cl4(NHR)2(PMe3)2, R = Et, Prn, and Bun. Direct Evidence Favoring an Internal Flip Mechanism for Cis−Trans Isomerization-Reference-Cited by-同舟云学术

W2Cl4(NR2)2(PR‘3)2 Molecules. 8. Synthesis and Structural Characterization of Both Cis Isomers of Stoichiometry W2Cl4(NHR)2(PMe3)2, R = Et, Prn, and Bun. Direct Evidence Favoring an Internal Flip Mechanism for Cis−Trans Isomerization

Published:1997-06-01 Issue:12 Volume:36 Page:2670-2677
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Cotton F. Albert¹,Dikarev Evgeny V.¹,Wong Wai-Yeung¹

Affiliation:

1. Department of Chemistry and Laboratory for Molecular Structure and Bonding, Texas A&M University, College Station, Texas 77843-3255

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic9700361

Reference12 articles.

1. W2Cl4(NHCMe3)2(PR3)2 Molecules (R3 = Me3, Et3, Prn3, Me2Ph). 2. 31P{1H} NMR Studies of Cis-Trans Isomerizations and Evidence That Suggests an Internal Flip of the W2 Unit

2. Preparation of octachloroditungstate(4-) and several of its derivatives

3. Preparation and characterization of sodium heptachloropentakis(THF)ditungstate(1-). A synthetically useful precursor for X3W.tplbond.WX3 compounds where X = CH2-tert-Bu, NMe2 and O-tert-Bu

4. Synthesis of a class of complexes containing tungsten-tungsten quadruple bonds

5. W2Cl4(NHR)2(PR‘3)2 Molecules. 3. Bidentate Phosphine Complexes of Bis(tert-butylamido)tetrachloroditungsten. Preparation and Structural Characterization of cis,cis-W2Cl4(NHCMe3)2(L-L) (L-L = dmpm, dmpe, dppm, dppe)

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