Cis−Trans Isomerization in Triply-Bonded Ditungsten Complexes: A Multitude of Possible Pathways
Author:
Affiliation:
1. Laboratory of Inorganic Chemistry, ETH Zentrum, CH-8092 Zurich, Switzerland
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic010470%2B
Reference20 articles.
1. W2Cl4(NHCMe3)2(PR3)2 Molecules (R3 = Me3, Et3, Prn3, Me2Ph). 2. 31P{1H} NMR Studies of Cis-Trans Isomerizations and Evidence That Suggests an Internal Flip of the W2 Unit
2. The W2Cl4(NHCMe3)2(PR 3)2 molecules (R 3=Me3, Et3, Pr n 3, Me2Ph) I. Their isomeric forms, interconversion proeesses, crystalline forms, and detailed molecular structures
3. W2Cl4(NHR)2(PR‘3)2 Molecules. 3. Bidentate Phosphine Complexes of Bis(tert-butylamido)tetrachloroditungsten. Preparation and Structural Characterization of cis,cis-W2Cl4(NHCMe3)2(L-L) (L-L = dmpm, dmpe, dppm, dppe)
4. W2Cl4(NR2)2(PR‘3)2 Molecules. 8. Synthesis and Structural Characterization of Both Cis Isomers of Stoichiometry W2Cl4(NHR)2(PMe3)2, R = Et, Prn, and Bun. Direct Evidence Favoring an Internal Flip Mechanism for Cis−Trans Isomerization
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