“yl”-Oxygen Exchange in Uranyl(VI) Ion: A Mechanism Involving (UO2)2(μ-OH)22+ via U–Oyl–U Bridge Formation
Author:
Affiliation:
1. Institute of Resource Ecology, Helmholtz-Zentrum Dresden-Rossendorf, Bautzner Landstraße 400, 01328, Dresden, Germany
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic201679e
Reference51 articles.
1. Oxo ligand functionalization in the uranyl ion (UO22+)
2. Chemical Speciation of the Uranyl Ion under Highly Alkaline Conditions. Synthesis, Structures, and Oxo Ligand Exchange Dynamics
3. Theoretical Study of Stable Trans and Cis Isomers in [UO2(OH)4]2- Using Relativistic Density Functional Theory
4. Theoretical Investigation of Uranyl Dihydroxide: Oxo Ligand Exchange, Water Catalysis, and Vibrational Spectra
5. Reactivity of the “yl”-Bond in Uranyl(VI) Complexes. 1. Rates and Mechanisms for the Exchange between the trans-dioxo Oxygen Atoms in (UO2)2(OH)22+ and Mononuclear UO2(OH)n2-n Complexes with Solvent Water
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