Reactivity of the “yl”-Bond in Uranyl(VI) Complexes. 1. Rates and Mechanisms for the Exchange between the trans-dioxo Oxygen Atoms in (UO2)2(OH)22+ and Mononuclear UO2(OH)n2-n Complexes with Solvent Water
Author:
Affiliation:
1. Department of Chemistry, Inorganic Chemistry, Royal Institute of Technology (KTH), Teknikringen 36, S-10044 Stockholm, Sweden
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic700817y
Reference28 articles.
1. The Formula of Uranyl Ion
2. The exchange reaction between uranyl ion and water in perchloric acid solution
3. The uranium(V)-catalysed exchange reaction between uranyl ion and water in perchloric acid solution
4. Chemical Speciation of the Uranyl Ion under Highly Alkaline Conditions. Synthesis, Structures, and Oxo Ligand Exchange Dynamics
5. Density functional theory investigation of the geometric and electronic structures of [UO2(H2O)m(OH)n]2−n(n + m = 5)
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