Clean Inversion of Configuration in the Pd-Catalyzed Cross-Coupling of 2-Bromo-1,3-dienes
Author:
Affiliation:
1. Herbert C. Brown Laboratories of Chemistry, Purdue University, 560 Oval Drive, West Lafayette, Indiana 47907-2084
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja0304392
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1. Highly Selective Synthesis of (E)-3-Methyl-1-trialkylsilyl-3-en-1-ynes via trans-Selective Alkynylation Catalyzed by Cl2Pd(DPEphos) and Stereospecific Methylation with Methylzincs Catalyzed by Pd(tBu3P)2
2. Callystatin A, a potent cytotoxic polyketide from the marine sponge, Callyspongia truncata
3. Asymmetric Total Synthesis of (−)-Callystatin A and (−)-20-epi-Callystatin A Employing Chemical and Biological Methods
4. Leptomycins A and B, new antifungal antibiotics. I. Taxonomy of the producing strain and their fermentation, purification and characterization.
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