Affiliation:
1. Key Laboratory of Optic-Electric Sensing and Analytic Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science & Technology, Qingdao 266042, China
Abstract
A phenol-mediated decarboxylative proton transfer of γ-methylidene-δ-valerolactones (GMDVs) was developed, affording the target polysubstituted (E)-2,4-pentadienoates in 99% yields with E/Z up to 99 : 1.
Funder
Taishan Scholar Project of Shandong Province
Natural Science Foundation of Shandong Province
National Natural Science Foundation of China
Qingdao University of Science and Technology
Publisher
Royal Society of Chemistry (RSC)