Ni(I) Intermediates Formed upon Activation of a Ni(II) α-Diimine Ethylene Polymerization Precatalyst with AlR3 (R = Me, Et, and iBu), AlR2Cl (R = Me, Et), and MMAO: A Comparative Study-Reference-Cited by-同舟云学术

Ni(I) Intermediates Formed upon Activation of a Ni(II) α-Diimine Ethylene Polymerization Precatalyst with AlR₃ (R = Me, Et, and ⁱBu), AlR₂Cl (R = Me, Et), and MMAO: A Comparative Study

Published:2022-04-08 Issue:8 Volume:41 Page:1015-1024
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Soshnikov Igor E.¹^ORCID,Semikolenova Nina V.¹,Bryliakov Konstantin P.¹,Antonov Artem A.¹,Talsi Evgenii P.¹^ORCID

Affiliation:

1. Boreskov Institute of Catalysis, Pr. Lavrentieva, 5, 630090, Novosibirsk, Russian Federation

Funder

Russian Science Foundation

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.organomet.2c00065

Reference48 articles.

1. New Pd(II)- and Ni(II)-Based Catalysts for Polymerization of Ethylene and .alpha.-Olefins

2. Synthesis of Branched Polyethylene Using (α-Diimine)nickel(II) Catalysts: Influence of Temperature, Ethylene Pressure, and Ligand Structure on Polymer Properties

3. Mechanistic Studies of Nickel(II) Alkyl Agostic Cations and Alkyl Ethylene Complexes: Investigations of Chain Propagation and Isomerization in (α-diimine)Ni(II)-Catalyzed Ethylene Polymerization

4. Semi‐Crystalline Polar Polyethylene: Ester‐Functionalized Linear Polyolefins Enabled by a Functional‐Group‐Tolerant, Cationic Nickel Catalyst

5. Understanding the Insertion Pathways and Chain Walking Mechanisms of α-Diimine Nickel Catalysts for α-Olefin Polymerization: A 13C NMR Spectroscopic Investigation

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